ASTM D4809 Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels
ASTM D4809 Test Method for Heat of Combustion of Liquid Hydrocarbon Fuels by Bomb Calorimeter (Precision Method)
4. Summary of Test Method
4.1 The heat of combustion is determined by burning a weighed sample in an oxygen-bomb calorimeter under controlled conditions. The temperature increase is measured by a temperature reading instrument which allows the precision of the test method to be met. The heat of combustion is calculated from temperature observations before, during, and after combustion, with proper allowance for thermochemical and heat-transfer corrections. Either isoperibol or adiabatic calorimeters may be used.

5. Significance and Use
5.1 The heat of combustion is a measure of the energy available from a fuel. A knowledge of this value is essential when considering the thermal efficiency of equipment for producing either power or heat.

5.2 The mass heat of combustion, that is, the heat of combustion per unit mass of fuel, is measured by this procedure. Its magnitude is particularly important to weight-limited vehicles such as airplanes, surface effect vehicles, and hydrofoils as the distance such craft can travel on a given weight of fuel is a direct function of the fuel’s mass heat of combustion and its density.

5.3 The volumetric heat of combustion, that is, the heat of combustion per unit volume of fuel, can be calculated by multiplying the mass heat of combustion by the density of the fuel (mass per unit volume). The volumetric heat of combustion, rather than the mass heat of combustion, is important to volume-limited craft such as automobiles and ships, as it is directly related to the distance traveled between refuelings.